1,3-Dipolar cyclisation reactions of nitriles with sterically encumbered cyclic triphosphanes: synthesis and electronic structure of phosphorus-rich heterocycles with tunable colour-Reference-Cited by-同舟云学术

1,3-Dipolar cyclisation reactions of nitriles with sterically encumbered cyclic triphosphanes: synthesis and electronic structure of phosphorus-rich heterocycles with tunable colour

Published:2024 Issue:30 Volume:15 Page:12006-12016
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Nascimento Mitchell A.¹^ORCID,LaPierre Etienne A.¹^ORCID,Patrick Brian O.²,Watson Jade E. T.¹^ORCID,Watanabe Lara³^ORCID,Rawson Jeremy³^ORCID,Hering-Junghans Christian⁴⁵^ORCID,Manners Ian¹^ORCID

Affiliation:

1. Department of Chemistry, University of Victoria, 3800 Finnerty Rd, Victoria, British Columbia, V8P 5C2, Canada

2. Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, British Columbia V6T 1Z1, Canada

3. Department of Chemistry and Biochemistry, University of Windsor, 401 Sunset Avenue, Windsor, Ontario N9B 3P4, Canada

4. Leibniz Institut für Katalyse e.V. (LIKAT), A.-Einstein-Str.3a, 18059 Rostock, Germany

5. Institut für Chemie, Otto-von-Guericke-Universität Magdeburg, Universitätsplatz 2, 39106 Magdeburg, Germany

Abstract

The acid-mediated cyclisation of sterically encumbered cyclic triphosphanes with nitriles provides access to five-membered cationic and neutral P3CN heterocycles with tuneable colour.

Funder

Natural Sciences and Engineering Research Council of Canada

Klaus Tschira Stiftung

University of Victoria

Government of Canada

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC02497D

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