Nickel-catalyzed cyanation of aryl halides and triflates using acetonitrile via C–CN bond cleavage assisted by 1,4-bis(trimethylsilyl)-2,3,5,6-tetramethyl-1,4-dihydropyrazine-Reference-Cited by-同舟云学术

Nickel-catalyzed cyanation of aryl halides and triflates using acetonitrile via C–CN bond cleavage assisted by 1,4-bis(trimethylsilyl)-2,3,5,6-tetramethyl-1,4-dihydropyrazine

Published:2019 Issue:4 Volume:10 Page:994-999
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Ueda Yohei¹²³⁴⁵^ORCID,Tsujimoto Nagataka¹²³⁴⁵^ORCID,Yurino Taiga¹²³⁴⁵,Tsurugi Hayato¹²³⁴⁵^ORCID,Mashima Kazushi¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Graduate School of Engineering Science

3. Osaka University

4. Toyonaka

5. Japan

Abstract

A catalyst system of [Ni(MeCN)₆](BF₄)₂, 1,10-phenanthroline, and 1,4-bis(trimethylsilyl)-2,3,5,6-tetramethyl-1,4-dihydropyrazine (Si–Me₄-DHP) assisted cyanation of aryl halides in acetonitrile to give the corresponding aryl nitriles.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C8SC04437F

Reference73 articles.

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4. Aromatic chloride to nitrile transformation: medicinal and synthetic chemistry

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