Enhanced Li+ conduction in perovskite Li3xLa2/3−x□1/3−2xTiO3 solid-electrolytes via microstructural engineering

Author:

Kwon Woo Ju12345,Kim Hyeongil6784,Jung Kyu-Nam1234,Cho Woosuk6784,Kim Sung Hyun59104,Lee Jong-Won123411ORCID,Park Min-Sik1213144ORCID

Affiliation:

1. New and Renewable Energy Research Division

2. Korea Institute of Energy Research

3. Daejeon 34129

4. Republic of Korea

5. Department of Chemical and Biological Engineering

6. Advanced Batteries Research Center

7. Korea Electronics Technology Institute

8. Seongnam 13509

9. Korea University

10. Seoul

11. Department of Advanced Energy and Technology

12. Department of Advanced Materials Engineering for Information and Electronics

13. Kyung Hee University

14. Yongin 17104

Abstract

To realize all-solid-state lithium batteries, it is necessary to develop solid electrolytes with high ionic conductivity and stability. A total Li+ conductivity as high as 4.8 × 10−4 S cm−1 can be achieved for perovskite Li3xLa(2/3)−x(1/3)−2xTiO3 at 25 °C via microstructural modifications.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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