Thiol-triggered deconstruction of bifunctional silyl ether terpolymers <i>via</i> an S<sub>N</sub>Ar-triggered cascade-Reference-Cited by-同舟云学术

Thiol-triggered deconstruction of bifunctional silyl ether terpolymers via an S_NAr-triggered cascade

Published:2023 Issue:33 Volume:14 Page:8869-8877
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Brown Christopher M.¹^ORCID,Husted Keith E. L.¹,Wang Yuyan¹,Kilgallon Landon J.¹,Shieh Peyton¹,Zafar Hadiqa¹^ORCID,Lundberg David J.¹²,Johnson Jeremiah A.¹³^ORCID

Affiliation:

1. Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA 02139, USA

2. Department of Chemical Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA 02139, USA

3. David H. Koch Institute for Integrative Cancer Research, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, USA

Abstract

Thiol-induced nucleophilic aromatic substitution of pentafluorophenyl sidechains is introduced as a strategy for the mild deconstruction of bifunctional silyl ether-containing soluble polymers and crosslinked “thermoset” plastics.

Funder

American Cancer Society

National Science Foundation

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC02868B

Reference65 articles.

1. Clip Chemistry: Diverse (Bio)(macro)molecular and Material Function through Breaking Covalent Bonds

2. Degradable Controlled-Release Polymers and Polymeric Nanoparticles: Mechanisms of Controlling Drug Release

3. Stimulus-Responsive Degradable Polylactide-Based Block Copolymer Nanoassemblies for Controlled/Enhanced Drug Delivery

4. Biodegradable Materials for Sustainable Health Monitoring Devices

Cited by 3 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Self-Amplified HF Release and Polymer Deconstruction Cascades Triggered by Mechanical Force;Journal of the American Chemical Society;2024-03-30

2. Poly(silyl ether)s as Degradable and Sustainable Materials: Synthesis and Applications;Molecules;2024-03-27

3. A Model Ensemble Approach Enables Data-Driven Property Prediction for Chemically Deconstructable Thermosets in the Low-Data Regime;ACS Central Science;2023-09-14