Role of solution concentration in formation kinetics of bromide perovskite thin films during spin-coating monitored by optical in situ metrology

Author:

Rehermann C.1ORCID,Schröder V.2,Flatken M.3ORCID,Ünlü F.4,Shargaieva O.1ORCID,Hoell A.2ORCID,Merdasa A.5,Mathies F.1ORCID,Mathur S.4ORCID,Unger E. L.167ORCID

Affiliation:

1. Department of Solution-Processed Materials and Devices, HySPRINT Innovation Lab, Helmholtz-Zentrum Berlin für Materialen und Energie GmbH, Kekuléstraße 5, 12489 Berlin, Germany

2. Helmholtz Zentrum für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin, Germany

3. Department Novel Materials and Interfaces for Photovoltaic Solar Cells, HySPRINT Innovation Lab, Helmholtz-Zentrum Berlin für Materialen und Energie GmbH, Kekuléstraße 5, 12489 Berlin, Germany

4. Inorganic and Materials Chemistry, University of Cologne, Greinstr. 6, 50939 Cologne, Germany

5. Department of Clinical Sciences Lund, Lund University, Sölvegatan 17, Lund, Sweden

6. Hybrid Materials: Formation and Scaling, IRIS Adlershof, Humboldt Universität zu Berlin, Am Großen Windkanal 2, 12489 Berlin, Germany

7. Chemical Physics and Nano Lund, Lund University, Lund, Sweden

Abstract

The solution chemistry of the precursor ink defines the formation kinetics of metal halide perovskites. Thus, rationalizing the formation process from solution via the deposition paves the way for high-quality thin films for optoelectronic devices.

Funder

Bundesministerium für Bildung und Forschung

Deutsche Forschungsgemeinschaft

Helmholtz Energy Materials Foundry

Helmholtz-Zentrum Berlin für Materialien und Energie

Universität Potsdam

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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