An acyclic zincagermylene: rapid activation of dihydrogen at sub-ambient temperature-Reference-Cited by-同舟云学术

An acyclic zincagermylene: rapid activation of dihydrogen at sub-ambient temperature

Published:2017 Issue:94 Volume:53 Page:12692-12695
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Juckel Martin M.¹²³,Hicks Jamie¹²³,Jiang Dandan⁴⁵⁶⁷⁸,Zhao Lili⁴⁵⁶⁷⁸,Frenking Gernot⁴⁵⁶⁷⁸^ORCID,Jones Cameron¹²³

Affiliation:

1. School of Chemistry

2. Monash University

3. Australia

4. Institute of Advanced Synthesis

5. School of Chemistry and Molecular Engineering

6. Jiangsu National Synergetic Innovation Center for Advanced Materials

7. Nanjing Tech University

8. Nanjing 211816

Abstract

The first zincagermylene (see picture) has been prepared and shown to have unprecedented reactivity for a germylene, with respect to the activation of dihydrogen; partially a result of its narrow HOMO–LUMO separation.

Funder

Australian Research Council

Air Force Office of Scientific Research

Nanjing Tech University

Natural Science Foundation of Jiangsu Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC08430G

Reference19 articles.

1. Main-group elements as transition metals

2. Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules

3. Interaction of Multiple Bonded and Unsaturated Heavier Main Group Compounds with Hydrogen, Ammonia, Olefins, and Related Molecules

4. Activation of H2by a Multiply Bonded Amido-Digermyne: Evidence for the Formation of a Hydrido-Germylene

5. A Digermyne with a Ge–Ge Single Bond That Activates Dihydrogen in the Solid State

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