Activation of [CrCl3{PPh2N(iPr)PPh2}] for the selective oligomerisation of ethene: a Cr K-edge XAFS study-Reference-Cited by-同舟云学术

Activation of [CrCl3{PPh2N(iPr)PPh2}] for the selective oligomerisation of ethene: a Cr K-edge XAFS study

Published:2016 Issue:16 Volume:6 Page:6237-6246
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Bartlett Stuart A.¹²³⁴⁵,Moulin Jerome⁶⁷⁸⁴,Tromp Moniek⁹¹⁰¹¹¹²,Reid Gillian⁶⁷⁸⁴,Dent Andy J.¹³²³⁴,Cibin Giannantonio¹³²³⁴,McGuinness David S.¹⁴¹⁵¹⁶¹⁷,Evans John¹²³⁴⁶

Affiliation:

1. Research Complex at Harwell

2. Rutherford Appleton Laboratory

3. Didcot

4. UK

5. Department of Chemistry

6. Chemistry

7. University of Southampton

8. Southampton

9. Van't Hoff Institute for Molecular Sciences

10. University of Amsterdam

11. 1090 GS Amsterdam

12. Netherlands

13. Diamond Light Source

14. School of Physical Sciences – Chemistry

15. University of Tasmania

16. Hobart 7001

17. Australia

Abstract

Freeze-quench XAFS reveals initial methylation of the Cr(iii) precursor prior to reduction to Lewis-acid dependent Cr(ii) species.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CY/C6CY00902F

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4. Selective ethylene oligomerization: Recent advances in chromium catalysis and mechanistic investigations

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