Highly regioselective α-alkylation of α,β,γ,δ-unsaturated aldehydes

Author:

Padmaja Venkata M. D.1234,Jangra Sachin1234,Appayee Chandrakumar1234ORCID

Affiliation:

1. Discipline of Chemistry

2. Indian Institute of Technology Gandhinagar

3. Gandhinagar

4. India

Abstract

The first regioselective MBH-type α-alkylation of α,β,γ,δ-unsaturated aldehydes is achieved using diarylcarbinols with an excellent E/Z selectivity under mild reaction conditions.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference52 articles.

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2. Recent Advances in Organocatalytic Methods for Asymmetric CC Bond Formation

3. Catalytic C–C Bond-Forming Multi-Component Cascade or Domino Reactions: Pushing the Boundaries of Complexity in Asymmetric Organocatalysis

4. Nucleophilic Phosphine Organocatalysis

5. Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes

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