Rapid reversible borane to boryl hydride exchange by metal shuttling on the carborane cluster surface-Reference-Cited by-同舟云学术

Rapid reversible borane to boryl hydride exchange by metal shuttling on the carborane cluster surface

Published:2017 Issue:8 Volume:8 Page:5399-5407
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Eleazer Bennett J.¹²³⁴,Smith Mark D.¹²³⁴,Popov Alexey A.⁵⁶⁷^ORCID,Peryshkov Dmitry V.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. University of South Carolina

3. Columbia

4. USA

5. Leibniz Institute for Solid State and Materials Research

6. 01069 Dresden

7. Germany

Abstract

The ruthenium carboranyl pincer complex featuring fluxional ”cage-walking“ of the metal center is an efficient catalyst for cyclooctane transfer dehydrogenation.

Funder

American Chemical Society Petroleum Research Fund

Division of Chemistry

H2020 Excellent Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC01846K

Reference79 articles.

1. Metallaboratranes Derived from a Triphosphanyl–Borane: IntrinsicC3 Symmetry Supported by a Z-Type Ligand

2. Analogies between Metallaboratranes, Triboronates, and Boron Pincer Ligand Complexes

3. Reversible H2 Addition across a Nickel–Borane Unit as a Promising Strategy for Catalysis

4. Functional group migrations between boron and metal centres within transition metal–borane and –boryl complexes and cleavage of H–H, E–H and E–E′ bonds

5. Syntheses of PBP Pincer Iridium Complexes: A Supporting Boryl Ligand

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