Cationic 5-phosphonio-substituted N-heterocyclic carbenes-Reference-Cited by-同舟云学术

Cationic 5-phosphonio-substituted N-heterocyclic carbenes

Published:2016 Issue:28 Volume:45 Page:11384-11396
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Schwedtmann Kai¹²³⁴,Schoemaker Robin¹²³⁴,Hennersdorf Felix¹²³⁴,Bauzá Antonio⁵⁶⁷⁸,Frontera Antonio⁵⁶⁷⁸^ORCID,Weiss Robert⁹¹⁰¹¹⁴,Weigand Jan J.¹²³⁴

Affiliation:

1. Department of Chemistry and Food Chemistry

2. TU Dresden

3. 01062 Dresden

4. Germany

5. Department of Chemistry

6. Universitat de les Illes Balears

7. Palma de Mallorca

8. Spain

9. Department of Chemistry and Pharmacy

10. Friedrich-Alexander-Universität Erlangen

11. 91054 Erlangen

Abstract

Cationic NHCs featuring a phosphonium moiety in the 5-position are prepared from the reaction of imidazolium salts with a tert. phosphane. They are used as ligands for the preparation of transition metal complexes, dehydrogenation reactions of prim. and sec. phosphanes and the preparation of a N-heterocyclic olefin (NHO).

Funder

European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT01871H

Reference82 articles.

1. Synthese und Eigenschaften von [Ph2(Carb)P]AlCl4 (Carb = 2,3-Dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-yliden) - ein stabiler Carben-Komplex des dreiwertigen Phosphors [1]

2. Carbene−Pnictinidene Adducts

3. Nature of the bonding in a carbene–phosphinidene: a main group analogue of a Fischer carbene complex? Isolation and characterisation of a bis(borane) adduct

4. Carbene-Stabilized Diphosphorus

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