Direct electrochemical defluorinative carboxylation of α-CF3 alkenes with carbon dioxide

Author:

Gao Xiao-Tong12345,Zhang Zheng12345,Wang Xin6789ORCID,Tian Jun-Song12345,Xie Shi-Liang12345,Zhou Feng12345ORCID,Zhou Jian12345ORCID

Affiliation:

1. Shanghai Key Laboratory of Green Chemistry and Chemical Processes

2. Shanghai Engineering Research Center of Molecular Therapeutics and New Drug Development

3. School of Chemistry and Molecular Engineering

4. East China Normal University

5. Shanghai 200062

6. College of Chemistry

7. Sichuan University

8. Chengdu

9. P. R. China

Abstract

A γ-carboxylation of α-CF3 alkenes with CO2 using platinum plate as both working cathode and nonsacrificial anode has been developed.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Ministry of Education of the People's Republic of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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