Why do dipole moments of HCl–water clusters fail to determine acid dissociation?-Reference-Cited by-同舟云学术

Why do dipole moments of HCl–water clusters fail to determine acid dissociation?

Published:2024 Issue:25 Volume:26 Page:17910-17917
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Zhuang Lei¹,Wang Jing¹,Wan Jianguo²^ORCID,Huang Chuanfu¹^ORCID

Affiliation:

1. School of Materials Science and Physics, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China

2. School of Physics, Nanjing University, Nanjing, Jiangsu 210093, China

Abstract

This paper quantitatively examines why dipole moments of HCl(H2O)n=1–8 cannot serve as the dissociation criterion for acid molecules using the Hirshfeld-I approach.

Funder

National Natural Science Foundation of China

China University of Mining and Technology

National Laboratory of Solid State Microstructures, Nanjing University

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP01316F

Reference51 articles.

1. Hydrated Acid Clusters

2. Aggregation-Induced Dissociation of HCl(H 2 O) 4 Below 1 K: The Smallest Droplet of Acid

3. High resolution spectroscopy of HCl–water clusters: IR bands of undissociated and dissociated clusters revisited

4. From clusters to biomolecules: electric dipole, structure and dynamics

5. Acidic protons before take-off: A comparative jet Fourier transform infrared study of small HCl– and HBr–solvent complexes

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