Rhodium(i)-catalyzed C6-selective C–H alkenylation and polyenylation of 2-pyridones with alkenyl and conjugated polyenyl carboxylic acids

Author:

Zhao Haoqiang12345,Xu Xin1234,Luo Zhenli1234,Cao Lei1234,Li Bohan1234,Li Huanrong1234,Xu Lijin12346ORCID,Fan Qinghua6784ORCID,Walsh Patrick J.5911011ORCID

Affiliation:

1. Department of Chemistry

2. Renmin University of China

3. Beijing 100872

4. China

5. Roy and Diana Vagelos Laboratories

6. Beijing National Laboratory for Molecular Sciences and Institute of Chemistry

7. Chinese Academy of Sciences

8. Beijing

9. Penn/Merck Laboratory for High-Throughput Experimentation

10. University of Pennsylvania

11. Philadelphia

Abstract

A versatile Rh(i)-catalyzed C6-selective decarbonylative C–H alkenylation of 2-pyridones with readily available alkenyl carboxylic acids has been developed.

Funder

China Scholarship Council

National Natural Science Foundation of China

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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