Synthesis and catalytic applications of 1,2,3-triazolylidene gold(i) complexes in silver-free oxazoline syntheses and C–H bond activation

Author:

Pretorius René12345,Fructos Manuel R.678910,Müller-Bunz Helge5111213,Gossage Robert A.123414,Pérez Pedro J.678910,Albrecht Martin12345

Affiliation:

1. Department of Chemistry and Biochemistry

2. University of Bern

3. CH-3012 Bern

4. Switzerland

5. School of Chemistry and Chemical Biology

6. Laboratorio de Catálisis Homogénea

7. Unidad Asociada al CSIC

8. CIQSO-Centro de Investigación en Química Sostenible and Departamento de Química

9. Universidad de Huelva

10. 21007 Huelva

11. University College Dublin

12. Dublin 4

13. Ireland

14. Department of Chemistry & Biology

Abstract

Novel triazolylidene gold(i) complexes were synthesized and activated by silver-free methodologies to generate catalysts for oxazoline synthesis and the C–H activation of arenes.

Funder

European Research Council

Consejería Economía, Innovación, Ciencia y Empleo, Junta de Andalucia

European Cooperation in Science and Technology

Swiss National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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