Evidence for tetranuclear bis-μ-oxo cubane species in molecular iridium-based water oxidation catalysts from XAS analysis-Reference-Cited by-同舟云学术

Evidence for tetranuclear bis-μ-oxo cubane species in molecular iridium-based water oxidation catalysts from XAS analysis

Published:2019 Issue:54 Volume:55 Page:7832-7835
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Bartlett Stuart A.¹²³^ORCID,Sackville Emma V.⁴⁵⁶³,Gibson Emma K.¹²³⁷⁸^ORCID,Celorrio Veronica¹²³^ORCID,Wells Peter P.¹²³⁷⁹^ORCID,Nachtegaal Maarten¹⁰¹¹¹²,Sheehan Stafford W.¹³¹⁴¹⁵^ORCID,Hintermair Ulrich⁴⁵⁶³^ORCID

Affiliation:

1. Diamond Light Source

2. Harwell Science and Innovation Campus

3. UK

4. Centre for Sustainable Chemical Technologies

5. University of Bath

6. Bath BA2 7AY

7. School of Chemistry

8. University of Glasgow

9. University of Southampton

10. Paul Scherrer Institute

11. 5232 Villigen

12. Switzerland

13. Catalytic Innovations

14. Fall River

15. USA

Abstract

Latest EXAFS results suggest a ‘dimer-of-dimers’ as the dominant resting state of Ir-pyalk WOCs in aqueous solution.

Funder

Royal Society

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC02088H

Reference40 articles.

1. Oxygen Electrochemistry as a Cornerstone for Sustainable Energy Conversion

2. Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation

3. Molecular Catalysts for Water Oxidation

4. Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction

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