Aerobically-initiated C(sp3)–H bond amination through the use of activated azodicarboxylates-Reference-Cited by-同舟云学术

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Aerobically-initiated C(sp3)–H bond amination through the use of activated azodicarboxylates

Published:2020 Issue:32 Volume:18 Page:6258-6264
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Shamsabadi André¹²³⁴,Maruani Antoine¹²³⁴,Ahmed Nehaal¹²³⁴,Chudasama Vijay¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University College London

3. London

4. UK

Abstract

In this article we report a procedure for α-C(sp³)–H amination of ethereal compounds through use of azodicarboxylates as the nitrogen source and freely-available atmospheric oxygen to access ethereal radical intermediates via aerobic C–H activation.

Funder

University College London

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/OB/D0OB01562H

Reference50 articles.

1. Green and sustainable chemistry: challenges and perspectives

2. The Green ChemisTREE: 20 years after taking root with the 12 principles

3. Collective Approach to Advancing C–H Functionalization

4. Analysis of the Structural Diversity, Substitution Patterns, and Frequency of Nitrogen Heterocycles among U.S. FDA Approved Pharmaceuticals

5. Catalytic C–H amination at its limits: challenges and solutions

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