ortho-Hydroxylation of aromatic acids by a non-heme FeVO species: how important is the ligand design?
Author:
Affiliation:
1. Department of Chemistry
2. Indian Institute of Technology-Bombay
3. Mumbai, India
Abstract
The mechanisms of the ortho-hydroxylation reaction of benzoic acid with two iron-oxo species have been explored, highlighting the importance of ligand design to achieve greater reactivity for these species.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2014/CP/C3CP55430A
Reference152 articles.
1. R. A. Sheldon and J. K.Kochi , Metal-Catalyzed Oxidations of Organic Compounds , Academic Press , New York , 1981
2. Recent Advances in Transition Metal Catalyzed Oxidation of Organic Substrates with Molecular Oxygen
3. Controlling the Regiospecific Oxidation of Aromatics via Active Site Engineering of Toluene para-Monooxygenase of Ralstonia pickettii PKO1
4. Crystal Structure of the Toluene/o-Xylene Monooxygenase Hydroxylase from Pseudomonas stutzeri OX1
5. Insight into the mechanism of aromatic hydroxylation by toluene 4-monooxygenase by use of specifically deuterated toluene and p-xylene
Cited by 35 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. DFT and TDDFT exploration on the role of pyridyl ligands with copper toward bonding aspects and light harvesting;Journal of Molecular Modeling;2023-11
2. Elusive Active Intermediates and Reaction Mechanisms of ortho-/ipso-Hydroxylation of Benzoic Acid by Hydrogen Peroxide Mediated by Bioinspired Iron(II) Catalysts;Inorganic Chemistry;2023-08-21
3. Electronic structures and ligand effect on redox potential of iron and cobalt complexes: a computational insight;Structural Chemistry;2023-02-13
4. Comparative oxidative ability of mononuclear and dinuclear high-valent iron–oxo species towards the activation of methane: does the axial/bridge atom modulate the reactivity?;Dalton Transactions;2023
5. Theoretical study of the formation of metal–oxo species of the first transition series with the ligand 14-TMC: driving factors of the “Oxo Wall”;Dalton Transactions;2023
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3