ortho-Hydroxylation of aromatic acids by a non-heme FeVO species: how important is the ligand design?
Author:
Affiliation:
1. Department of Chemistry
2. Indian Institute of Technology-Bombay
3. Mumbai, India
Abstract
The mechanisms of the ortho-hydroxylation reaction of benzoic acid with two iron-oxo species have been explored, highlighting the importance of ligand design to achieve greater reactivity for these species.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2014/CP/C3CP55430A
Reference152 articles.
1. R. A. Sheldon and J. K.Kochi , Metal-Catalyzed Oxidations of Organic Compounds , Academic Press , New York , 1981
2. Recent Advances in Transition Metal Catalyzed Oxidation of Organic Substrates with Molecular Oxygen
3. Controlling the Regiospecific Oxidation of Aromatics via Active Site Engineering of Toluene para-Monooxygenase of Ralstonia pickettii PKO1
4. Crystal Structure of the Toluene/o-Xylene Monooxygenase Hydroxylase from Pseudomonas stutzeri OX1
5. Insight into the mechanism of aromatic hydroxylation by toluene 4-monooxygenase by use of specifically deuterated toluene and p-xylene
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