Investigation of Pb–B Bonding in PbB2(BO)n (n = 0–2): Transformation from Aromatic PbB2 to Pb[B2(BO)2]−/0 Complexes with BB Triple Bonds

Author:

Chen Qiang12ORCID,Chen Wei-Jia3ORCID,Wu Xin-Yao1,Chen Teng-Teng34,Yuan Rui-Nan1,Lu Hai-Gang12,Yuan Dao-Fu35ORCID,Li Si-Dian12ORCID,Wang Lai-Sheng3ORCID

Affiliation:

1. Institute of Molecular Science, Key Laboratory of Materials for Energy Conversion and Storage of Shanxi Province, Shanxi University, Taiyuan 030006, People's Republic of China

2. Key Laboratory of Chemical Biology and Molecular Engineering of Ministry of Education, Shanxi University, Taiyuan 030006, People's Republic of China

3. Department of Chemistry, Brown University, Providence, Rhode Island 02912, USA

4. Department of Chemistry, The Hong Kong University of Science and Technology (HKUST), Clear Water Bay, Hong Kong SAR, China

5. Hefei National Research Center for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei 230026, China

Abstract

Joint photoelectron spectroscopy and first-principles theory investigations indicate that the Pb-doped PbB2(BO)n clusters (n = 0−2) undergo a transformation from σ + π doubly aromatic triangle PbB2 to PbB4(BO)2−/0 complexes with a B≡B triple bond.

Funder

National Natural Science Foundation of China

Shanxi University

Publisher

Royal Society of Chemistry (RSC)

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