Fundamental electron-transfer and proton-coupled electron-transfer properties of Ru(iv)-oxo complexes-Reference-Cited by-同舟云学术

Fundamental electron-transfer and proton-coupled electron-transfer properties of Ru(iv)-oxo complexes

Published:2019 Issue:35 Volume:48 Page:13154-13161
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kotani Hiroaki¹²³⁴⁵^ORCID,Shimomura Hinatsu¹²³⁴⁵,Horimoto Momoka¹²³⁴⁵,Ishizuka Tomoya¹²³⁴⁵^ORCID,Shiota Yoshihito⁶⁷⁸⁵,Yoshizawa Kazunari⁶⁷⁸⁵^ORCID,Yanagisawa Sachiko⁹¹⁰¹¹⁵,Kawahara-Nakagawa Yuka⁹¹⁰¹¹⁵,Kubo Minoru⁹¹⁰¹¹⁵,Kojima Takahiko¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Graduate School of Pure and Applied Sciences

3. University of Tsukuba and CREST (JST)

4. Tsukuba

5. Japan

6. Institute for Materials Chemistry and Engineering

7. Kyushu University

8. Fukuoka 819-0395

9. Graduate School of Life Science

10. University of Hyogo

11. Hyogo 678-1297

Abstract

Reorganization energies (λ) of electron transfer (ET) and proton-coupled ET (PCET) from electron donors to isolated Ru^IV(O) complexes were determined to be in the range of 1.70–1.88 eV (ET) and 1.20–1.26 eV (PCET).

Funder

Japan Society for the Promotion of Science

Core Research for Evolutional Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT02734C

Reference52 articles.

1. Dioxygen Activation by Enzymes with Mononuclear Non-Heme Iron Active Sites

2. Non-Heme Fe(IV)–Oxo Intermediates