Potential rules for stable transition metal hexafluorides with high oxidation states under high pressures-Reference-Cited by-同舟云学术

Potential rules for stable transition metal hexafluorides with high oxidation states under high pressures

Published:2023 Issue:9 Volume:25 Page:6726-6732
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Ma Shiyin¹^ORCID,Zhao Liang¹^ORCID,Li Shichang²,Gao Tao¹,Peng Feng³^ORCID

Affiliation:

1. Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, China

2. School of Science, Chongqing University of Posts and Telecommunications, Chongqing 400065, China

3. College of Physics and Electronic Information, Luoyang Normal University, Luoyang 471934, China

Abstract

Three potential guiding rules to explore the stability and the high oxidation state with +6 in Transition Metal (TM) fluorides have been proposed. A collection of new TMF6 with space group Pnma, showing +6 oxidation state have been predicted.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D2CP05418C

Reference68 articles.

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3. Synthesis and Structure of Formally Hexavalent Palladium Complexes

4. How Far Can We Go? Quantum-Chemical Investigations of Oxidation State +IX

5. Gold as a 6p-Element in Dense Lithium Aurides

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