Mixed triorganobismuthines RAr2Bi [Ar = C6F5, 2,4,6-(C6F5)3C6H2] and hypervalent racemic Bi-chiral diorganobismuth(iii) bromides RArBiBr (Ar = C6F5, Mes, Ph) with the ligand R = 2-(Me2NCH2)C6H4. Influences of the organic substituent-Reference-Cited by-同舟云学术

Mixed triorganobismuthines RAr2Bi [Ar = C6F5, 2,4,6-(C6F5)3C6H2] and hypervalent racemic Bi-chiral diorganobismuth(iii) bromides RArBiBr (Ar = C6F5, Mes, Ph) with the ligand R = 2-(Me2NCH2)C6H4. Influences of the organic substituent

Published:2016 Issue:23 Volume:45 Page:9419-9428
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Olaru Marian¹²³⁴⁵,Nema Mihai G.¹²³⁴⁵,Soran Albert¹²³⁴⁵,Breunig Hans J.⁶⁷⁸⁹,Silvestru Cristian¹²³⁴⁵

Affiliation:

1. Departamentul de Chimie

2. Centrul de Chimie Supramoleculară Organică şi Organometalică (CCSOOM)

3. Facultatea de Chimie şi Inginerie Chimică

4. Universitatea Babeş-Bolyai

5. 400028 Cluj-Napoca

6. Institut für Anorganische und Physikalische Chemie

7. Universität Bremen

8. D-28334 Bremen

9. Germany

Abstract

RAr₂Bi and chiral RArBiBr were structurally characterized; N–Bi bond distances in RArBiBr appear to be similar regardless of the electronic properties of the Ar ligand.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT05074J

Reference56 articles.

1. Organobismuth Chemistry, ed. H. Suzuki and Y. Matano, Elsevier Science B.V., Amsterdam, 2001

2. Bismuth-Mediated Organic Reactions, in Topics in Current Chemistry, ed. T. Ollevier, Springer, Berlin, Heidelberg, 2012, vol. 312

3. Hypervalent organoantimony and -bismuth compounds with pendant arm ligands

4. Structural Chemistry of Bismuth Compounds. I. Organobismuth Derivatives

5. Bismuth in Organic Transformations

Cited by 12 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Organic Compounds of Bismuth: Synthesis, Structure, and Applications;Russian Journal of Coordination Chemistry;2021-12

2. Catalytic Hydrodefluorination via Oxidative Addition, Ligand Metathesis, and Reductive Elimination at Bi(I)/Bi(III) Centers;Journal of the American Chemical Society;2021-08-06

3. Organometallic Compounds of Arsenic, Antimony and Bismuth;Reference Module in Chemistry, Molecular Sciences and Chemical Engineering;2021

4. Pnictogen bonding in coordination chemistry;Coordination Chemistry Reviews;2020-09

5. High Lewis Acidity at Planar, Trivalent, and Neutral Bismuth Centers;Organometallics;2020-07-15