Mechanistic insights into on-surface reactions from isothermal temperature-programmed X-ray photoelectron spectroscopy

Author:

Grossmann Lukas12ORCID,Hocke Manuela1,Galeotti Gianluca2,Contini Giorgio34ORCID,Floreano Luca5ORCID,Cossaro Albano56ORCID,Ghosh Amit7ORCID,Schmittel Michael7ORCID,Rosen Johanna8,Heckl Wolfgang M.12,Björk Jonas8ORCID,Lackinger Markus12ORCID

Affiliation:

1. Physics Department, Technical University of Munich, James-Franck-Str. 1, 85748 Garching, Germany

2. Deutsches Museum, Museumsinsel 1, 80538 Munich, Germany

3. Istituto di Struttura della Materia-CNR (ISM-CNR), Via Fosso del Cavaliere 100, Roma, Italy

4. Department of Physics, University of Rome Tor Vergata, Via della Ricerca Scientifica 1, 00133, Roma, Italy

5. Istituto Officina dei Materiali Consiglio Nazionale delle Ricerche, S.S. 14, km 163.5, Trieste, 34149, Italy

6. Department of Chemical and Pharmaceutical Sciences, Università degli Studi di Trieste, via L. Giorgieri 1, 34100, Trieste, Italy

7. Center of Micro and Nanochemistry and (Bio)Technology, Organische Chemie I, Universität Siegen, Adolf-Reichwein-Str. 2, 57068 Siegen, Germany

8. Linköping University, Department of Physics, Chemistry and Biology, IFM, 581 83 Linköping, Sweden

Abstract

The temporal evolution of the reactant concentrations as measured by XPS for different temperature profiles reveals that the debromination of organic molecules on Ag(111) is activated by Ag adatoms.

Funder

Göran Gustafssons Stiftelse för Naturvetenskaplig och Medicinsk Forskning

Deutsche Forschungsgemeinschaft

Vetenskapsrådet

Horizon 2020 Framework Programme

Publisher

Royal Society of Chemistry (RSC)

Cited by 2 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Real-Time Imaging of On-Surface Ullmann Polymerization Reveals an Inhibiting Effect of Adatoms;Journal of the American Chemical Society;2024-08-21

2. Kinetics of On-Surface Dechlorinated Aryl–Aryl Coupling;The Journal of Physical Chemistry C;2024-07-17

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