Oxidation of methane by an N-bridged high-valent diiron–oxo species: electronic structure implications on the reactivity-Reference-Cited by-同舟云学术

Oxidation of methane by an N-bridged high-valent diiron–oxo species: electronic structure implications on the reactivity

Published:2015 Issue:34 Volume:44 Page:15232-15243
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ansari Mursaleem¹²³⁴,Vyas Nidhi¹²³⁴,Ansari Azaj¹²³⁴,Rajaraman Gopalan¹²³⁴

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Bombay

3. Mumbai-400076

4. India

Abstract

Methane activation by dinuclear high-valent iron–oxo species: do we need two metals to activate such inert bonds? Our theoretical study using DFT methods where electronic structure details and mechanistic aspects are established answers this intriguing question.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01060H

Reference85 articles.

1. X-ray Crystal Structure of Alcohol Products Bound at the Active Site of Soluble Methane Monooxygenase Hydroxylase

2. Dynamics of Alkane Hydroxylation at the Non-Heme Diiron Center in Methane Monooxygenase

3. Dioxygen Activation in Soluble Methane Monooxygenase

4. Cytochrome P450 Catalyzed Oxidative Hydroxylation of Achiral Organic Compounds with Simultaneous Creation of Two Chirality Centers in a Single CH Activation Step

5. Mechanism of cytochrome c peroxidase. O-Benzoylhydroxylamine as an analog of hydrogen peroxide

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