Mechanistic details of ethylene polymerization reaction using methallyl nickel(ii) catalysts-Reference-Cited by-同舟云学术

Mechanistic details of ethylene polymerization reaction using methallyl nickel(ii) catalysts

Published:2018 Issue:35 Volume:20 Page:22915-22925
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Ortega Daniela E.¹²³,Cortés-Arriagada Diego⁴⁵⁶⁷³^ORCID,Toro-Labbé Alejandro¹²³^ORCID

Affiliation:

1. Laboratorio de Química Teórica Computacional (QTC), Pontificia Universidad Católica de Chile

2. Santiago 9900087

3. Chile

4. Programa Institucional de Fomento a la Investigación

5. Desarrollo e Innovación

6. Universidad Tecnológica Metropolitana

7. Santiago

Abstract

We present a mechanistic study of the ligand functionalization of bulky boron co-activators on neutral methallyl Ni(ii) catalysts for polyethylene production. This provides a blueprint for the development and design of catalysts with a high degree of tunability in a more efficient way.

Funder

Fondo Nacional de Desarrollo Científico y Tecnológico

FP7 People: Marie-Curie Actions

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CP/C8CP03955K

Reference69 articles.

1. Ziegler-Natta Catalysis

2. R. H. Crabtree , The Organometallic Chemistry of the Transition Metals , 4th edn, 2005 , pp. 87–124