Two stereocentered HKR of anti-β,β′-diphenylpropanoxirane and anti-3-phenylethyloxiranes catalysed by Co(iii)(salen)-OAc complex: enantioselective synthesis of (+)-sertraline and (+)-naproxen-Reference-Cited by-同舟云学术

Two stereocentered HKR of anti-β,β′-diphenylpropanoxirane and anti-3-phenylethyloxiranes catalysed by Co(iii)(salen)-OAc complex: enantioselective synthesis of (+)-sertraline and (+)-naproxen

Published:2018 Issue:12 Volume:42 Page:10414-10420
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Kamble Rohit B.¹²³⁴⁵,Devalankar Dattatraya⁶⁷⁸⁹,Suryavanshi Gurunath¹²³⁴^ORCID

Affiliation:

1. Chemical Engineering and Process Development Division

2. National Chemical Laboratory

3. Pune-411008

4. India

5. Academy of Scientific & Innovative Research

6. Postdoctoral Fellow at Department of Radiology

7. UAB Hospital

8. Birmingham AL

9. USA

Abstract

Two stereocentered HKR of anti-β,β′-diphenylmethyloxirane and anti-3-phenylethyloxiranes gives enantiopure anti-1,2-diols and oxiranes. This method is utilised for the synthesis of (+)-sertraline and (+)-naproxen.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C8NJ01616J

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