Influence of the tetraalkoxysilane crosslinker on the properties of polysiloxane-based elastomers prepared by the Lewis acid-catalysed Piers-Rubinsztajn reaction-Reference-Cited by-同舟云学术

Influence of the tetraalkoxysilane crosslinker on the properties of polysiloxane-based elastomers prepared by the Lewis acid-catalysed Piers-Rubinsztajn reaction

Published:2021 Issue:34 Volume:12 Page:4934-4941
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Hickman Andrew M.¹²^ORCID,Chmel Nikola³^ORCID,Cameron Neil R.²⁴^ORCID,Keddie Daniel J.⁵^ORCID,Schiller Tara L.¹²^ORCID

Affiliation:

1. WMG, University of Warwick, Coventry CV4 7AL, UK

2. Department of Materials Science and Engineering, Monash University, 22 Alliance Lane, Clayton 3800, Victoria, Australia

3. Department of Chemistry, University of Warwick, Coventry CV4 7AL, UK

4. School of Engineering, University of Warwick, Coventry CV4 7AL, UK

5. Faculty of Science and Engineering University of Wolverhampton, Wolverhampton WV1 1LY, UK

Abstract

We investigate the influence of the tetrafunctional alkoxysilan R-groups, with a range of sterics and electronics. This is through a solvent free polysiloxane network formation under ambient conditions using Lewis acid catalysed Piers-Rubinsztajn (PR) reaction.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2021/PY/D1PY00872B

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