Theoretical study on the reaction mechanism and selectivity of acetylene semi-hydrogenation on Ni–Sn intermetallic catalysts-Reference-Cited by-同舟云学术

Theoretical study on the reaction mechanism and selectivity of acetylene semi-hydrogenation on Ni–Sn intermetallic catalysts

Published:2019 Issue:3 Volume:21 Page:1384-1392
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Rao De-Ming¹²³⁴⁵,Sun Tao¹²³⁴,Yang Yu-Sen¹²³⁴,Yin Pan¹²³⁴,Pu Min¹²³⁴^ORCID,Yan Hong¹²³⁴^ORCID,Wei Min¹²³⁴^ORCID

Affiliation:

1. State Key Laboratory of Chemical Resource Engineering

2. Beijing University of Chemical Technology

3. Beijing 100029

4. China

5. Institute of Science and Technology Strategy

Abstract

A density functional theory study has been carried out to investigate the mechanism of acetylene hydrogenation on six surfaces of Ni–Sn IMCs, and the geometric effects towards ethylene selectivity was revealed.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C8CP06032K

Reference54 articles.

1. Partial hydrogenation of acetylene using highly stable dispersed bimetallic Pd–Ga/MgO–Al2O3 catalyst

2. Al13Fe4 as a low-cost alternative for palladium in heterogeneous hydrogenation

3. Selective hydrogenation of acetylene in the presence of ethylene on zeolite-supported bimetallic catalysts

4. Intermetallic NixMy(M= Ga and Sn) Nanocrystals: A Non-precious Metal Catalyst for Semi-Hydrogenation of Alkynes

5. Pd−Ga Intermetallic Compounds as Highly Selective Semihydrogenation Catalysts

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