7-endo selenocyclization reactions on chiral 3-prenyl and 3-cinnamyl-2-hydroxymethylperhydro-1,3-benzoxazine derivatives. A way to enantiopure 1,4-oxazepanes-Reference-Cited by-同舟云学术

7-endo selenocyclization reactions on chiral 3-prenyl and 3-cinnamyl-2-hydroxymethylperhydro-1,3-benzoxazine derivatives. A way to enantiopure 1,4-oxazepanes

Published:2015 Issue:34 Volume:13 Page:9118-9126
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Nieto Javier¹²³⁴⁵,Andrés Celia¹²³⁴⁵,Pérez-Encabo Alfonso¹²³⁴⁵

Affiliation:

1. Instituto CINQUIMA and Departamento de Química Orgánica

2. Facultad de Ciencias

3. Universidad de Valladolid

4. 47011 Valladolid

5. Spain

Abstract

A short and efficient procedure for the preparation of a variety of enantiopure 1,4-oxazepanes with up to three stereocenters by 7-endo-cyclization in perhydro-1,3-benzoxazine derivatives is developed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C5OB01297J

Reference76 articles.

1. I. Ninomiya , T.Naito and O.Miyata, in Comprehensive Heterocyclic Chemistry II, ed. A. R. Katritzky, C. W. Rees and E. F. V. Scriven, Pergamon, Oxford, 1996, vol. 9, ch. 9, pp. 217–231

2. Synthesis and evaluation of N-substituted 1,4-oxazepanyl sordaricins as selective fungal EF-2 inhibitors

3. Sordarin Oxazepine Derivatives as Potent Antifungal Agents

4. Benzo- and pyrido-1,4-oxazepin-5-ones and -thiones: synthesis and structure-activity relationships of a new series of H1-antihistamines

5. Characterization of the Histamine H4 Receptor Binding Site. Part 1. Synthesis and Pharmacological Evaluation of Dibenzodiazepine Derivatives

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