Self-aggregation, H-bonding, and photoresponse in film and solution states of azobenzene containing polyurea

Author:

Erekath Swathi1,Chordiya Kalyani23ORCID,Vidhya K. V.1,Kahaly Mousumi Upadhyay23ORCID,Kalpathy Sreeram K.1ORCID

Affiliation:

1. Department of Metallurgical and Materials Engineering, Indian Institute of Technology Madras, Chennai-600036, India

2. ELI-ALPS, ELI-HU Non-Profit Ltd., Wolfgang Sandner utca 3., Szeged, H-6728, Hungary

3. Institute of Physics, University of Szeged, Dóm tér 9, H-6720 Szeged, Hungary

Abstract

Photoisomerization, aggregation, and UV-visible absorbance of cis and trans azo-polyurea thin films and solution are investigated. Hydrogen bonding and changes in excitation energies render cis azo-PU more stable in solution than in the film state.

Funder

Indian Institute of Technology Madras

European Regional Development Fund

Nemzeti Kutatási, Fejlesztési és Innovaciós Alap

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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