Evaluating the electronic structure of formal LnIIions in LnII(C5H4SiMe3)31−using XANES spectroscopy and DFT calculations-Reference-Cited by-同舟云学术

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Evaluating the electronic structure of formal LnIIions in LnII(C5H4SiMe3)31−using XANES spectroscopy and DFT calculations

Published:2017 Issue:9 Volume:8 Page:6076-6091
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Fieser Megan E.¹²³^ORCID,Ferrier Maryline G.⁴⁵³^ORCID,Su Jing⁴⁵³^ORCID,Batista Enrique⁴⁵³^ORCID,Cary Samantha K.⁴⁵³^ORCID,Engle Jonathan W.⁴⁵³⁶⁷^ORCID,Evans William J.¹²³^ORCID,Lezama Pacheco Juan S.⁸⁹³^ORCID,Kozimor Stosh A.⁴⁵³^ORCID,Olson Angela C.⁴⁵³^ORCID,Ryan Austin J.¹²³^ORCID,Stein Benjamin W.⁴⁵³^ORCID,Wagner Gregory L.⁴⁵³^ORCID,Woen David H.¹²³^ORCID,Vitova Tonya¹⁰¹¹¹²¹³,Yang Ping⁴⁵³^ORCID

Affiliation:

1. University of California

2. Irvine

3. USA

4. Los Alamos National Laboratory

5. Los Alamos

6. University of Wisconsin

7. Madison

8. Stanford University

9. Palo Alto

10. Karlsruhe Institute of Technology

11. Institute for Nuclear Waste Disposal

12. 76021 Karlsruhe

13. Germany

Abstract

Ln^II(C₅H₄SiMe₃)¹⁻have been characterized by XANES and DFT.

Funder

National Science Foundation

U.S. Department of Energy

Helmholtz Association

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC00825B

Reference128 articles.

1. Synthesis of a Crystalline Molecular Complex of Y2+, [(18-crown-6)K][(C5H4SiMe3)3Y]

2. Expanding Rare-Earth Oxidation State Chemistry to Molecular Complexes of Holmium(II) and Erbium(II)

3. Completing the Series of +2 Ions for the Lanthanide Elements: Synthesis of Molecular Complexes of Pr2+, Gd2+, Tb2+, and Lu2+

4. Valence, Oxidation Number, and Formal Charge: Three Related but Fundamentally Different Concepts

5. Oxidation State, A Long-Standing Issue!

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