Anti-Markovnikov terminal and gem-olefin hydrosilylation using a κ4-diimine nickel catalyst: selectivity for alkene hydrosilylation over ether C

Anti-Markovnikov terminal and gem-olefin hydrosilylation using a κ4-diimine nickel catalyst: selectivity for alkene hydrosilylation over ether C–O bond cleavage

Published:2019 Issue:2 Volume:48 Page:461-467
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Rock Christopher L.¹²³⁴,Trovitch Ryan J.¹²³⁴^ORCID

Affiliation:

1. School of Molecular Sciences

2. Arizona State University

3. Tempe

4. USA

Abstract

The hydrosilylation of terminal alkenes, allyl ethers, and gem-olefins has been demonstrated using (^Ph2PPrDI)Ni between 25 and 70 °C.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT04608E

Reference75 articles.

1. Cross-coupling of organosilanes with organic halides mediated by a palladium catalyst and tris(diethylamino)sulfonium difluorotrimethylsilicate

2. B. Marciniec , Comprehensive Handbook on Hydrosilylation , 1st edn, Pergamon Press , New York, USA , 1992

3. The Addition of Silicon Hydrides to Olefinic Double Bonds. Part II. The Use of Group VIII Metal Catalysts

4. Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view

5. Advances in Base-Metal-Catalyzed Alkene Hydrosilylation

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