Sodium phosphaethynolate, Na(OCP), as a “P” transfer reagent for the synthesis of N-heterocyclic carbene supported P3and PAsP radicals-Reference-Cited by-同舟云学术

Sodium phosphaethynolate, Na(OCP), as a “P” transfer reagent for the synthesis of N-heterocyclic carbene supported P3and PAsP radicals

Published:2014 Issue:4 Volume:5 Page:1545-1554
ISSN:2041-6520
Container-title:Chem. Sci.
language:en
Short-container-title:Chem. Sci.

Author:

Tondreau Aaron M.¹²,Benkő Zoltán¹²,Harmer Jeffrey R.³⁴⁵,Grützmacher Hansjörg¹²⁶⁷⁸

Affiliation:

1. Department of Chemistry and Applied Biosciences

2. ETH Zürich, Switzerland

3. Centre for Advanced Imaging

4. University of Queensland

5. , Australia

6. Lehn Institute of Functional Materials (LIFM)

7. Sun Yat-Sen University

8. 510275 Guangzhou, China

Abstract

From Na(OCP) as a “P” transfer reagent, the radicals (NHC–P–E–P–NHC) (E = P, As) were synthesized and characterized as donor–acceptor adducts by EPR spectroscopy and DFT computations.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/SC/C3SC53140F

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