Electrochemical oxidative rearrangement of tetrahydro-β-carbolines in a zero-gap flow cell

Author:

Zheng Yiting12,Cheung Yuen Tsz3,Liang Lixin3ORCID,Qiu Huiying3,Zhang Lei2,Tsang Anson1,Chen Qing13ORCID,Tong Rongbiao3ORCID

Affiliation:

1. Department of Mechanical and Aerospace Engineering, and Energy Institute, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, P. R. China

2. State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Jiaotong University, Xi'an, 710049, China

3. Department of Chemistry, The Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou), The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong SAR, China

Abstract

A zero-gap flow cell was designed for the first electro-oxidative rearrangement of tetrahydro-β-carbolines to spirooxindoles with high yield, faradaic efficiency and productivity when LiBr was discovered as a bi-functional mediator and catalyst.

Funder

Southern Marine Science and Engineering Guangdong Laboratory

National Natural Science Foundation of China

Xi’an Jiaotong University

Research Grants Council, University Grants Committee

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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