Chemoselective and stereospecific iodination of alkynes using sulfonium iodate(i) salt
Author:
Affiliation:
1. Department of Chemistry
2. Malaviya National Institute of Technology (MNIT)
3. Jaipur-302 017
4. India
5. INSPIRE Faculty
Abstract
The sulfonium iodate(i) electrophilc reagent efficiently promoted the stereodivergent iodination of alkynes. The chemoselective iodination was effectively realized by switching the solvent system to access the 1-iodoalkyne and (E)-vicinal-diiodoalkenes.
Funder
Science and Engineering Research Board
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/OB/C7OB03076B
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