Ru(ii)- and Ru(iv)-dmso complexes catalyze efficient and selective aqueous-phase nitrile hydration reactions under mild conditions-Reference-Cited by-同舟云学术

Ru(ii)- and Ru(iv)-dmso complexes catalyze efficient and selective aqueous-phase nitrile hydration reactions under mild conditions

Published:2021 Issue:37 Volume:45 Page:17339-17346
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Trivedi Manoj¹²^ORCID,Dubey Santosh Kumar³,Kaur Gurmeet⁴,Rath Nigam P.⁵

Affiliation:

1. Department of Chemistry, University of Delhi, Delhi-110007, India

2. Department of Chemistry, Sri Venkateswara College, University of Delhi, NewDelhi-110021, India

3. Department of Chemistry, Institute of Integrated & Honors Studies, Kurukshetra University, Kurukshetra-136119, India

4. Department of Chemistry, SGTB Khalsa College, University of Delhi, Delhi 110 007, India

5. Department of Chemistry & Biochemistry and Centre for Nanoscience, University of Missouri-St. Louis, One University Boulevard, St. Louis, MO 63121-4499, USA

Abstract

Synthesis and characterization of new water-soluble Ru(ii)- and Ru(iv)-dmso complexes are reported which show good efficiency and selectivity for aqueous-phase nitrile hydration at 60 °C in air. Best performance is achieved using complex [RuCl2(dmso)3(NH3)]·PF6·Cl (3).

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/NJ/D1NJ03041H

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