New insight into the polymerization mechanism of 1,3-dienes cationic polymerization. IV. Mechanism of unsaturation loss in the polymerization of isoprene-Reference-Cited by-同舟云学术

New insight into the polymerization mechanism of 1,3-dienes cationic polymerization. IV. Mechanism of unsaturation loss in the polymerization of isoprene

Published:2017 Issue:5 Volume:8 Page:926-935
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Rozentsvet Victor A.¹²³⁴,Kozlov Valery G.¹²³⁴,Sablina Nelly A.¹²³⁴,Stotskaya Olesya A.¹²³⁴,Peruch Frederic⁵⁶⁷⁸⁹,Kostjuk Sergei V.¹⁰¹¹¹²

Affiliation:

1. Institute of Ecology of the Volga River Basin

2. Russian Academy of Science

3. Togliatti

4. Russia

5. LCPO

6. UMR 5629

7. CNRS

8. University of Bordeaux

9. Pessac Cedex

10. Research Institute for Physical Chemical Problems of the Belarusian State University

11. Minsk

12. Belarus

Abstract

The mechanism of obtaining a polymer with reduced unsaturation is proposed, which includes the formation of branched structures.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2017/PY/C6PY01736C

Reference55 articles.

1. Yu. B. Monakov and G. A.Tolstikov, Catalytic Polymerization of 1,3-Dienes, Nauka, Moscow, 1990

2. J. E. Mark , B.Erman and F. R.Eirich, Science and Technology of Rubber, Elsevier Academic Press, Amsterdam, 2005

3. V. A. Rozentsvet , V. G.Kozlov and Yu. B.Monakov, Cationic Polymerization of conjugated dienes, Nauka, Moscow, 2011

4. Cationic polymerization of isoprene in the presence of the TiCl4-trichloroacetic acid catalyst system

5. Cationic polyisoprene: Synthesis, structure, and some properties

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