Mechanistic insights into the reactions of hydride transfer versus hydrogen atom transfer by a trans-dioxoruthenium(vi) complex
Author:
Affiliation:
1. Department of Chemistry and Nano Science
2. Center for Biomimetic System
3. Ewha Womans University
4. Seoul 120-750
5. Korea
6. Department of Chemistry
7. Goa University
8. Goa
9. India
Abstract
Valuable insights into the hydride-transfer mechanism and C–H bond activation reactions by high-valent trans-dioxoruthenium(vi) species is provided.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00809C
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3. P. R. Ortiz de Montellano , Cytochrome P450: Structure, Mechanism, and Biochemistry, Kluwer Academic/Plenum Publishers, New York, 3rd edn, 2005
4. Non-Heme Fe(IV)–Oxo Intermediates
5. The biology and chemistry of high-valent iron–oxo and iron–nitrido complexes
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