Contributions of inner and outer coordination sphere bonding in determining the strength of substituted phenolic pyrazoles as copper extractants
Author:
Affiliation:
1. EaStCHEM School of Chemistry
2. University of Edinburgh
3. Edinburgh
4. UK
5. Cytec Industries
6. Stamford
7. USA
Abstract
Simple phenolic pyrazoles have strengths and selectivities comparable to oxime extractants which account for a quarter of the world's copper production.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04055H
Reference18 articles.
1. Small molecule analogs for the specific iron-binding site of lactoferrin: a single-crystal x-ray structure of bis(methanol)bis[2-(5-methylpyrazol-3-yl)phenolato]iron(III) nitrate-methanol and spectroscopic studies on iron(III) phenolate complexes
2. Dioxomolybdenum(VI) Complexes with Pyrazole Based Aryloxide Ligands: Synthesis, Characterization and Application in Epoxidation of Olefins
3. Oxorhenium(V) Complexes with Pyrazole Based Aryloxide Ligands and Application in Olefin Epoxidation
4. Phenolic pyrazoles: Versatile polynucleating ligands
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