Rh-catalyzed regio-switchable cross-coupling of <i>gem</i>-difluorinated cyclopropanes with allylboronates to structurally diverse fluorinated dienes-Reference-Cited by-同舟云学术

Rh-catalyzed regio-switchable cross-coupling of gem-difluorinated cyclopropanes with allylboronates to structurally diverse fluorinated dienes

Published:2022 Issue:42 Volume:13 Page:12419-12425
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zeng Yaxin¹,Yang Hui¹,Du Jiayi¹,Huang Qin²,Huang Guoliang²^ORCID,Xia Ying¹^ORCID

Affiliation:

1. West China School of Public Health and West China Fourth Hospital, West China-PUMC C.C. Chen Institute of Health, and State Key Laboratory of Biotherapy, Sichuan University, Chengdu 610041, China

2. Department of Biomedical Engineering, School of Medicine, Tsinghua University, Beijing 100084, China

Abstract

Rh-catalyzed regio-switchable cross-coupling reactions of gem-difluorinated cyclopropanes with allylboronates have been developed. Fluorinated 1,4-dienes, 1,5-dienes and 1,3-dienes are produced in good yields with excellent regioselectivity.

Funder

Thousand Young Talents Program of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC04118A

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