From bis(imidazole-2-thion-4-yl)phosphane to a flexible P-bridged bis(NHC) ligand and its silver complex
Author:
Affiliation:
1. Institut für Anorganische Chemie
2. Rheinische Friedrich-Wilhelms-Universität Bonn
3. 53121 Bonn, Germany
Abstract
Synthesis of the first P(v)-bridged bis(NHC) ligand 7 was achieved via deprotonation of P(v)-functionalized bis(imidazolium) salt 6, which was obtained via oxidative desulfurization of bis(imidazole-2-thion-4-yl)phosphane 2.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT02479F
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