The interplay of chirality and restricted rotation: stabilisation of chiral, frustrated mesophases over a wide thermal range-Reference-Cited by-同舟云学术

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The interplay of chirality and restricted rotation: stabilisation of chiral, frustrated mesophases over a wide thermal range

Published:2024 Issue:17 Volume:20 Page:3685-3694
ISSN:1744-683X
Container-title:Soft Matter
language:en
Short-container-title:Soft Matter

Author:

Bhat Sachin A.¹^ORCID,Yelamaggad Channabasaveshwara V.¹²³

Affiliation:

1. Centre for Nano and Soft Matter Sciences Arkavathi, Survey No. 7, Shivanapura, Dasanapura Hobli, Bengaluru–562162, India

2. Department of Chemistry, Manipal Institute of Technology, Manipal Academy of Higher Education, Manipal 576104, India

3. SJB Institute of Technology, Health & Education City, Kengeri, Bengaluru – 560060, India

Abstract

Chiral dimers formed by linking cholesterol to phenyl 3-(4-(n-alkoxy)phenyl)propiolate via ω-oxyalkanoyloxy spacer exhibit odd–even effect, stabilizing SmA, N*, BPI/II, & TGBC* phases. TGBC* phase width increases with longer terminal tails.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SM/D4SM00126E

Reference29 articles.

1. Symmetric and non-symmetric liquid crystal dimers with branched terminal alkyl chains: racemic and chiral

2. Dimesogenic compounds consisting of cholesterol and fluorinated azobenzene moieties: dependence of liquid crystal properties on spacer length and fluorination of the terminal tail

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