Simple but effective: thermally stable Cu–ESiMe3via NHC ligation-Reference-Cited by-同舟云学术

Simple but effective: thermally stable Cu–ESiMe3via NHC ligation

Published:2015 Issue:39 Volume:51 Page:8361-8364
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Fard Mahmood Azizpoor¹²³⁴,Weigend Florian⁵⁶⁷⁸⁹,Corrigan John F.¹²³⁴¹⁰

Affiliation:

1. Department of Chemistry

2. The University of Western Ontario

3. London

4. Canada

5. Institut für Nanotechnologie

6. Karlsruher Institut für Technologie (KIT)

7. 76344 Eggenstein-Leopoldshafen

8. Germany

9. Institut für Physikalische Chemie

10. Centre for Advanced Materials and Biomaterials Research

Abstract

The reaction of the N-heterocyclic carbene stabilized complex [(IPr)Cu–SSiMe₃] (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) with mercuric(ii) acetate affords the heterometallic cluster [{(IPr)CuS}₂Hg] (illustrated).

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC00940E

Reference35 articles.

1. New Copper and Silver Trimethylsilylchalcogenolates

2. Synthesis and Characterization of Tris(trialkylphosphine)copper(I)trimethylsilylchalcogenolates

3. Metal-Chalcogenolate Complexes with Silyl Functionalities: Synthesis and Reaction Chemistry

4. Copper and Silver Complexes Containing the S(SiMe2S)22 Ligand: Efficient Entries into Heterometallic Sulfido Clusters

5. Copper Chalcogenolate Complexes as Precursors to Ternary Nanoclusters: Synthesis and Characterization of [Hg15Cu20S25(nPr3P)18]

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