Correlation between structure and mixed ionic–electronic conduction mechanism for (La1−xSrx)CoO3−δ using synchrotron X-ray analysis and first principles calculations

Author:

Itoh Takanori12345,Inukai Manabu67895,Kitamura Naoto12345,Ishida Naoya12345,Idemoto Yasushi12345,Yamamoto Takashi101112135

Affiliation:

1. Department of Pure and Applied Chemistry

2. Faculty of Science and Technology

3. Tokyo University of Science

4. Noda City

5. Japan

6. Department of Materials Science and Engineering

7. Faculty of Engineering

8. Nagoya Institute of Technology

9. Nagoya City

10. Department of Mathematical and Material Sciences

11. Faculty of Integrated Arts and Sciences

12. The University of Tokushima

13. Tokushima City

Abstract

The ionic–electronic conduction of (La1−xSrx)CoO3−δ is studied by experiments and calculations. The spin state transition occurred concomitantly with the metal–insulator transition.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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