Magneto-structural correlations in Ni(ii) [2 × 2] metallogrids featuring a variable number of μ-aquo or μ-hydroxo extra bridges-Reference-Cited by-同舟云学术

Magneto-structural correlations in Ni(ii) [2 × 2] metallogrids featuring a variable number of μ-aquo or μ-hydroxo extra bridges

Published:2019 Issue:5 Volume:21 Page:917-924
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Marino Nadia¹²³⁴^ORCID,Bruno Rosaria¹²³⁴,Bentama Abdeslem⁵⁶⁷⁸⁹,Pascual-Álvarez Alejandro¹⁰¹¹¹²,Lloret Francesc¹⁰¹¹¹²^ORCID,Julve Miguel¹⁰¹¹¹²^ORCID,De Munno Giovanni¹²³⁴^ORCID

Affiliation:

1. Dipartimento di Chimica e Tecnologie Chimiche

2. Università della Calabria

3. Cosenza

4. Italy

5. Laboratoire de Chimie Organique Appliquée

6. Faculté des Sciences Techniques de Fès

7. Université Sidi Mohammed Ben Abdellah

8. Fès

9. Morocco

10. Departament de Química Inorgànica/Instituto de Ciencia Molecular (ICMol)

11. 46980 Paterna

12. Spain

Abstract

Cationic [2 × 2]-grids of nickel(ii) and dppn exhibit strong intramolecular antiferromagnetic interactions due to complementary effects between pyridazine and aquo/hydroxo bridges.

Funder

Ministero dell’Istruzione, dell’Università e della Ricerca

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CE/C8CE01894D

Reference77 articles.

1. The Synthesis of Some Pyridylpyridazines and -pyrimidines1

2. 3,6-Bis(2′-pyridyl)pyridazine (L) and its deprotonated form (L − H+)−as ligands for {(acac)2Run+} or {(bpy)2Rum+}: investigation of mixed valency in [{(acac)2Ru}2(μ-L − H+)]0and [{(bpy)2Ru}2(μ-L − H+)]4+by spectroelectrochemistry and EPR