Strained surface siloxanes as a source of synthetically important radicals-Reference-Cited by-同舟云学术

Strained surface siloxanes as a source of synthetically important radicals

Published:2015 Issue:122 Volume:5 Page:100618-100624
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Ward Antony J.¹²³⁴,Lesic Rebecca A.¹²³⁴,Proschogo Nicholas⁵⁶³⁴,Masters Anthony F.¹²³⁴,Maschmeyer Thomas¹²³⁴

Affiliation:

1. Laboratory of Advanced Catalysis for Sustainability

2. School of Chemistry

3. The University of Sydney

4. Australia

5. Mass Spectrometry Unit

6. School of Chemistry F11

Abstract

The calcination of pure amorphous silica at temperatures up to 850 °C results in the formation of strained siloxane rings which are capable of undergoing homolytic cleavage to generate radicals when in the presence of an appropriate substrate.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA20399F

Reference44 articles.

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2. M. J. Perkins , Radical Chemistry, Ellis Horwood, New York, 1994

3. A. Ravve , Principles of Polymer Chemistry, Kluwer Academic, New York, 2nd edn, 2000

4. Phenothiazine cation radical formation on silica, silica-alumina and alumina

5. D. L. Griscom , in Defects in SiO2 and Related Dielectrics: Science and Technology, ed. G. Pacchioni, L. Skuja and D. L. Griscom, Kluwer, Dordrecht, 2000

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