Synthesis and characterization of rare-earth metal guanidinates stabilized by amine-bridged bis(phenolate) ligands and their application in the controlled polymerization of rac-lactide and rac-β-butyrolactone-Reference-Cited by-同舟云学术

Synthesis and characterization of rare-earth metal guanidinates stabilized by amine-bridged bis(phenolate) ligands and their application in the controlled polymerization of rac-lactide and rac-β-butyrolactone

Published:2015 Issue:65 Volume:5 Page:53161-53171
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Zeng Tinghua¹²³⁴⁵,Qian Qinqin¹²³⁴⁵,Zhao Bei¹²³⁴⁵,Yuan Dan¹²³⁴⁵,Yao Yingming¹²³⁴⁵,Shen Qi¹²³⁴⁵

Affiliation:

1. Key Laboratory of Organic Synthesis of Jiangsu Province and Suzhou Key Laboratory of Macromolecular Design and Precision Synthesis

2. College of Chemistry

3. Chemical Engineering and Materials Science

4. Soochow University

5. Suzhou

Abstract

Eight rare-earth metal guanidinates supported by a versatile family of bridged bis(phenolate) ligands were synthesized, and their application in initiating stereoselective ROP of rac-lactide and rac-β-butyrolactone were investigated and compared.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA10151D

Reference73 articles.

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3. Controlled ring-opening polymerisation of cyclic esters: polymer blocks in self-assembled nanostructures