Electron belt-to-σ-hole switch of noncovalently bound iodine(i) atoms in dithiocarbamate metal complexes-Reference-Cited by-同舟云学术

Electron belt-to-σ-hole switch of noncovalently bound iodine(i) atoms in dithiocarbamate metal complexes

Published:2021 Issue:10 Volume:8 Page:2505-2517
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Zelenkov Lev E.¹²³⁴⁵^ORCID,Eliseeva Anastasiya A.¹²³⁴^ORCID,Baykov Sergey V.¹²³⁴^ORCID,Suslonov Vitalii V.¹²³⁴^ORCID,Galmés Bartomeu⁶⁷⁸⁹,Frontera Antonio⁶⁷⁸⁹^ORCID,Kukushkin Vadim Yu.¹²³⁴¹⁰^ORCID,Ivanov Daniil M.¹²³⁴^ORCID,Bokach Nadezhda A.¹²³⁴^ORCID

Affiliation:

1. Institute of Chemistry

2. Saint Petersburg State University

3. Saint Petersburg

4. Russian Federation

5. Department of Physics and Engineering

6. Department of Chemistry

7. Universitat de les Illes Balears

8. 07122 Palma de Mallorca

9. Spain

10. Laboratory of Crystal Engineering of Functional Materials

Abstract

The nature of metals in the isostructural series of dithiocarbamate complexes affects the electron belt-to-σ-hole switch of noncovalently bound iodine(i) leading to either semicoordination, or halogen bonding.

Funder

Russian Foundation for Basic Research

Saint Petersburg State University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QI/D1QI00314C

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1. Nucleophilicity of Oximes Based upon Addition to a Nitrilium closo-Decaborate Cluster

2. Anagostic Interactions and Catalytic Activities of Sterically Bulky Benzannulated N-Heterocyclic Carbene Complexes of Nickel(II)