Toward a mechanistic understanding of oxidative homocoupling: the Glaser–Hay reaction
Author:
Affiliation:
1. Institute of Chemical Research of Catalonia (ICIQ)
2. 43007 Tarragona, Spain
3. Henkel AG & Co. KGaA
4. 40589 Düsseldorf, Germany
5. Departament de Química
6. Universitat Autònoma de Barcelona
7. Barcelona, Spain
Abstract
The full reaction mechanism for the copper catalyzed oxidative coupling of two terminal alkynes is computationally characterized with DFT methods
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2014/CY/C4CY00322E
Reference97 articles.
1. R. Bates , Organic Synthesis using Transition Metals , Wiley-Blackwell , Sheffield, UK , 2000
2. J. F. Hartwig , Organotransition Metal Chemistry: From Bonding to Catalysis , University Science Books , U.S., Sausalito, US , 2009
3. The Nobel Prize in Chemistry 2010 – Richard F.Heck and E.-I.Negishi , Akira Suzuki Nobelprize.org. 6 June 2010. http://nobelprize.org/nobel_prizes/chemistry/laureates/2010/
4. Copper-Catalyzed Aerobic Oxidative Amidation of Terminal Alkynes: Efficient Synthesis of Ynamides
5. Nickel-Catalyzed Oxidative Coupling Reactions of Two Different Terminal Alkynes Using O2as the Oxidant at Room Temperature: Facile Syntheses of Unsymmetric 1,3-Diynes
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