Vibrational energy pooling via collisions between asymmetric stretching excited CO2: a quasi-classical trajectory study on an accurate full-dimensional potential energy surface-Reference-Cited by-同舟云学术

Vibrational energy pooling via collisions between asymmetric stretching excited CO2: a quasi-classical trajectory study on an accurate full-dimensional potential energy surface

Published:2021 Issue:42 Volume:23 Page:24165-24174
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Lu Dandan¹²^ORCID,Chen Jun³,Guo Hua²^ORCID,Li Jun¹^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering & Chongqing Key Laboratory of Theoretical and Computational Chemistry, Chongqing University, Chongqing 401331, China

2. Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, New Mexico, 87131, USA

3. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

Abstract

QCT calculations revealed that multi-vibrational-quantum processes are significant due to energy flow in the collisional complex formed by enhanced dipole–dipole interaction between asymmetric stretching excited CO2 molecules.

Funder

National Natural Science Foundation of China

Multidisciplinary University Research Initiative

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP03687D

Reference62 articles.

1. Vibrational Energy Transfer Modeling of Nonequilibrium Polyatomic Reaction Systems

2. S. H.Robertson , Unimolecular Kinetics: Parts 2 and 3: Collisional Energy Transfer and the Master Equation , Elsevier , 2019