Facile water oxidation by dinuclear mixed-valence CoIII/CoII complexes: the role of coordinated water-Reference-Cited by-同舟云学术

Facile water oxidation by dinuclear mixed-valence CoIII/CoII complexes: the role of coordinated water

Published:2021 Issue:40 Volume:50 Page:14257-14263
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Dey Atanu¹^ORCID,Guha Anku¹,Kumar Vierandra¹,Bawari Sumit¹,Narayanan Tharangattu N.¹^ORCID,Chandrasekhar Vadapalli¹²^ORCID

Affiliation:

1. Tata Institute of Fundamental Research Hyderabad, Gopanpally, Hyderabad-500107, India

2. Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur-208016, India

Abstract

Dinuclear mixed-valence CoIIICoII complexes, [CoIIICoII(LH2)2(X)(H2O)] (X = OAc or Cl), containing coordinated water show better OER activity than complex [CoIIICoII(LH2)2(vanillin)] that does not possess coordinated water.

Funder

Department of Atomic Energy, Government of India

Department of Science and Technology, Ministry of Science and Technology, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT01910D

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